You cannot have everything in main toolbar.
And a button for inserting NULLs should never be in main toolbar imho as it is relevant for Data grids only.
Its current location (in context menu as well as on Ctrl+Shift+N hot key) is perfect.
Ctr+Shit+N uses two hands, one i use for mouse.
Ok, main toolbar is not right place, but it should be at list on cell edit window, just button (NULL).
Or on context menu.